There is basically no relationship between ovulation and breast pain in women. Ovulation in women is mostly located 14 days before menstruation. After ovulation, female estrogen can change and the endometrium can thicken, if the egg cell cannot combine with the sperm to form a fertilized egg, the thickened endometrium will shed and be discharged, which is usually called menstruation. Ovulation is not related to breast pain.